Hole and Electron Doping of Topochemically Reduced Ni(I)/Ru(II) Insulating Ferromagnetic Oxides

نویسندگان

چکیده

LaxSr2-xNiRuO6, LaxSr4-xNiRuO8, and LaxSr3-xNiRuO7 are, respectively, the n = ∞, 1, 2 members of (Lax/2Sr1-(x/2))nSr(Ni0.5Ru0.5)nO3n+1 compositional series. Reaction with CaH2, in case LaxSr2-xNiRuO6 perovskite phases, or Zr oxygen getters LaxSr4-xNiRuO8 Ruddlesden-Popper yields corresponding topochemically reduced (Lax/2Sr1-(x/2))nSr(Ni0.5Ru0.5)nO3n-1 compounds (LaxSr2-xNiRuO4, LaxSr4-xNiRuO6, LaxSr3-xNiRuO5), which contain Ni Ru cations square-planar coordination sites. The x 1 each series (LaSrNiRuO4, LaSr3NiRuO6, LaSr2NiRuO5) exhibit insulating ferromagnetic behavior at low temperature, attributable to exchange couplings between Ni1+ Ru2+ centers they contain. Increasing La3+ concentration (x > 1) leads a reduction some Ru1+ suppression state (lower Tc, saturated ferromagnet moment). In contrast, increasing Sr2+ < oxidizes Ru3+ enhances coupling (increased increased moment) for ∞ samples but appears have no influence on magnetic ordering temperature samples. doping are discussed basis superexchange direct centers.

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ژورنال

عنوان ژورنال: Inorganic Chemistry

سال: 2021

ISSN: ['0020-1669', '1520-510X']

DOI: https://doi.org/10.1021/acs.inorgchem.1c02265